Germany beat European champions Spain 1-0 in Tuesday night's friendly thanks to a late goal from Toni Kroos.
Wayne Rooney capped his Wembley milestone with a landmark goal as England came from behind to beat Slovenia 3 -1.
Milivoje Novakovic's first-half double gave Slovenia a 2-0 European Championship qualifying win in Lithuania.
Spain took the first steps on the road to recovery from their World Cup woe with a 5-1 win over Macedonia in Valencia.
UEFA have approved the launch of a Nations League from 2018, with the new tournament to be played every second year.
Slovenia's hopes of qualifying for the World Cup were dashed by a 1-0 defeat in Switzerland on Tuesday night.
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