Germany beat European champions Spain 1-0 in Tuesday night's friendly thanks to a late goal from Toni Kroos.
Neymar scored all four goals as Brazil thrashed Japan 4-0 in an international friendly in Singapore.
Japan coach Alberto Zaccheroni has quit after taking full responsibility for the Asian champions' exit from World Cup.
Alberto Zaccheroni says he will discuss his future with the Japan Football Association after their World Cup failure.
Jackson Martinez helped fire Colombia into the last 16 as Group C winners after a 4-1 victory over Japan in Cuiaba.
Greece produced a dogged defensive performance to draw 0-0 with Japan in Group C after Kostas Katsouranis was sent off.
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