Alireza Jahanbakhsh was NEC Nijmegen's hero with a two-goal haul helping to beat Ajax, condemning Roda JC to the drop.
Real Madrid's Super Cup clash with Sevilla starts a stunning season of live European football on Sky Sports 5.
Ajax clinched their fourth successive Eredivisie title with a 1-1 draw against Heracles Almelo on Sunday.
Roda JC's place in the Eredivisie's bottom three was confirmed on Saturday as they fell to a 3-0 defeat to FC Twente.
FC Twente boosted their hope of a top-two finish in the Eredivisie with a 2-0 win at NAC Breda, while PSV were thrashed.
Ajax moved a step closer to their fourth consecutive Eredivisie title with a 2-0 win away at struggling RKC.
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