Alireza Jahanbakhsh was NEC Nijmegen's hero with a two-goal haul helping to beat Ajax, condemning Roda JC to the drop.
Real Madrid's Super Cup clash with Sevilla starts a stunning season of live European football on Sky Sports 5.
Ajax clinched their fourth successive Eredivisie title with a 1-1 draw against Heracles Almelo on Sunday.
Zwolle stunned Ajax 5-1 in the Dutch Cup final to claim the first piece of major silverware in their history.
Ajax will have to wait to get their hands on the Eredivisie trophy after Feyenoord matched their victory on Sunday.
FC Groningen boosted their hopes of securing a Europa League play-off berth on Friday with a 1-0 victory at PEC Zwolle.
Live only on
© 2014 BSkyB