Alvaro Morata scored as Spain beat Ukraine 1-0 in Friday's European Qualifiers, while Slovakia won to stay top of Group C.
Germany beat European champions Spain 1-0 in Tuesday night's friendly thanks to a late goal from Toni Kroos.
Spain took the first steps on the road to recovery from their World Cup woe with a 5-1 win over Macedonia in Valencia.
UEFA have approved the launch of a Nations League from 2018, with the new tournament to be played every second year.
Find out more about Sky Sports' live coverage of 250 European Qualifiers this season.
Romania pipped Turkey to second spot in Group D and a place in the World Cup play-offs by defeating Estonia 2-0.
Turkey won 2-0 in Estonia to move into second place in World Cup qualifying Group D.
San Marino claimed the first European Championship qualifying point in their history after a stalemate with Estonia.
Hungary moved into second place in their World Cup qualifying group with a comfortable 5-1 victory at home to Estonia.
Chile romp to win, USA seal Bosnian win, Colombia beat Serbia, Asamoah Gyan is Ghana hero
Holland can go a long way to securing a place at the World Cup finals in Brazil next summer with victory over Romania.
Holland recorded their fifth World Cup Group D qualifying win with a 3-0 victory over Estonia in Amsterdam.
Gabon caused upset as they held Portugal to a draw, while Didier Drogba scored as Ivory Coast triumphed in Austria.
Turkey got their World Cup qualifying campaign up and running with an emphatic 3-0 victory over 10-man Estonia in Istanbul.
Robin van Persie was on target for Holland while Romania and Hungary were also victorious.
Holland were stunned by Belgium, Argentina beat Germany and Russia drew in Fabio Capello's first match as manager.
Tarmo Kink is being linked with a move to Hungarian side Gyori ETO after being released by Middlesbrough.
Dublin is getting ready for a party atmosphere as Republic of Ireland look to seal Euro 2012 qualification on Tuesday night.