Germany beat European champions Spain 1-0 in Tuesday night's friendly thanks to a late goal from Toni Kroos.
Spain took the first steps on the road to recovery from their World Cup woe with a 5-1 win over Macedonia in Valencia.
UEFA have approved the launch of a Nations League from 2018, with the new tournament to be played every second year.
Romania pipped Turkey to second spot in Group D and a place in the World Cup play-offs by defeating Estonia 2-0.
Turkey won 2-0 in Estonia to move into second place in World Cup qualifying Group D.
San Marino claimed the first European Championship qualifying point in their history after a stalemate with Estonia.
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