England will play Denmark in a friendly on March 5 at Wembley.
The Football Association had already confirmed friendlies with Chile and Germany this year, and the Danes will be the first opposition of 2014 as Roy Hodgson prepares his squad for the World Cup.
The match has been organised as part of an arrangement which saw England play Denmark in Copenhagen in February 2011.
England have the better head to head record between the two, winning 11 of their previous 18 meetings.
Denmark came second in Group B in World Cup qualifying but missed out on a play-off berth as they finished with the weakest record of the nine runners-up.